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NEET Chemistry: Equilibrium Practice Questions

15 free multiple-choice questions on Equilibrium for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. For the equilibrium A(g) + B(g) ⇌ C(g) + D(g), if the concentration of reactant A is increased, the equilibrium will shift towards which side?

    • AThe left side (reactants)
    • BThe right side (products)
    • CThe side with the higher concentration of A
    • DThe side with fewer moles of gas
    Show answer & explanation

    Correct answer: B — The right side (products)

    According to Le Chatelier's principle, if the concentration of a reactant (A) is increased, the system attempts to counteract this change by consuming the added reactant. This causes the equilibrium to shift in the forward direction to consume A and form more products.

  2. Q2. In an equilibrium reaction, the value of the equilibrium constant (K_c) is directly related to the ratio of which quantities?

    • AConcentrations of reactants and products
    • BConcentration of products only
    • CConcentration of excess reactant
    • DConcentration of solvent
    Show answer & explanation

    Correct answer: A — Concentrations of reactants and products

    The equilibrium constant (K_c) is the ratio of the product concentrations to the reactant concentrations at equilibrium.

  3. Q3. If the system is at equilibrium, what does this imply about the net change in the amount of substance over time?

    • AThe amount of substance is continuously decreasing
    • BThe amount of substance depends on the initial conditions
    • CThere is no net change in the amount of substance
    • DThe amount of substance is continuously increasing
    Show answer & explanation

    Correct answer: C — There is no net change in the amount of substance

    Equilibrium, whether static or dynamic, implies that the macroscopic properties, such as the total amount of substance, are constant over time.

  4. Q4. A solution has a pH of 12. What is the nature of this solution?

    • ANeutral
    • BSlightly acidic
    • CStrongly acidic
    • DStrongly basic
    Show answer & explanation

    Correct answer: D — Strongly basic

    A pH greater than 7 indicates a basic solution. Since 12 > 7, the solution is strongly basic.

  5. Q5. What is the definition of pH in terms of hydrogen ion concentration?

    • ApH = [OH⁻]
    • BpH = 10⁽-pOH)
    • CpH = [H⁺]
    • DpH = log[H⁺]
    Show answer & explanation

    Correct answer: C — pH = [H⁺]

    pH is defined as the negative logarithm (base 10) of the hydrogen ion concentration, i.e., pH = -log[H⁺].

  6. Q6. When a product is removed from a system at equilibrium, the system will shift to:

    • AThe left side (reactants).
    • BThe right side (products).
    • CThe reactants will be depleted.
    • DThe same position (no shift).
    Show answer & explanation

    Correct answer: B — The right side (products).

    If a product is removed, the system attempts to replace the removed product by shifting the equilibrium to the right, thus increasing the concentration of the remaining products to re-establish equilibrium.

  7. Q7. The concentration of hydrogen ions (H⁺) in a solution is directly proportional to which measure?

    • AThe pOH of the solution
    • BThe molar mass of the solute
    • CThe temperature of the solution
    • DThe electrical conductivity of the solution
    Show answer & explanation

    Correct answer: D — The electrical conductivity of the solution

    The concentration of H⁺ ions dictates the acidity. Higher H⁺ concentration corresponds to higher acidity and, consequently, a lower pH (or higher pOH).

  8. Q8. In a system that is at dynamic equilibrium, which of the following statements is true regarding the reaction rates?

    • AThe net rate of reaction is zero and no reactions are occurring
    • BThe rate of the forward reaction is equal to the rate of the reverse reaction
    • CThe rate of the forward reaction is zero
    • DThe rate of the reverse reaction is zero
    Show answer & explanation

    Correct answer: B — The rate of the forward reaction is equal to the rate of the reverse reaction

    Dynamic equilibrium is a state where the rates of the forward and reverse reactions are equal, meaning the concentrations of reactants and products remain constant, but the reactions themselves are still occurring at equal rates.

  9. Q9. Which of the following statements is true regarding the behavior of an acidic solution compared to a basic solution?

    • AThe concentration of H⁺ ions is zero in basic solutions.
    • BAcidic solutions have a lower pH than basic solutions.
    • CThe concentration of OH⁻ ions is higher in acidic solutions.
    • DBasic solutions have a higher concentration of H⁺ ions than acidic solutions.
    Show answer & explanation

    Correct answer: B — Acidic solutions have a lower pH than basic solutions.

    Acidic solutions have a higher concentration of H⁺ ions (and lower OH⁻ concentration) compared to basic solutions. Lower pH corresponds to higher acidity.

  10. Q10. Which of the following changes will favor the forward reaction in the equilibrium A + B ⇌ C if the forward reaction is endothermic?

    • ADecreasing the temperature.
    • BIncreasing the concentration of C.
    • CDecreasing the concentration of A.
    • DIncreasing the temperature.
    Show answer & explanation

    Correct answer: D — Increasing the temperature.

    For an endothermic reaction (where heat is a reactant), increasing the temperature shifts the equilibrium to the right (forward direction) to consume the added heat.

  11. Q11. In a system undergoing a reversible chemical reaction, what is the defining characteristic of dynamic equilibrium?

    • AThe reaction proceeds irreversibly
    • BThe concentrations of reactants and products are constant
    • CThe reaction stops completely
    • DThe forward and reverse reaction rates are equal
    Show answer & explanation

    Correct answer: D — The forward and reverse reaction rates are equal

    Dynamic equilibrium is a state where the forward and reverse reaction rates are equal, meaning the net concentrations of reactants and products remain constant, even though the reactions are still occurring simultaneously.

  12. Q12. Which of the following best describes the state of concentrations of reactants and products when a system is at dynamic equilibrium?

    • AThe concentrations of all species remain constant
    • BProducts are consumed faster than reactants are formed
    • CThe reaction has stopped entirely
    • DReactants are consumed faster than products are formed
    Show answer & explanation

    Correct answer: A — The concentrations of all species remain constant

    In dynamic equilibrium, although reactions are still occurring, the net change in concentrations of reactants and products is zero, meaning their concentrations are constant over time.

  13. Q13. If a reaction is at equilibrium, it implies that the system is reversible. What does reversibility mean in this context?

    • AThe reaction is irreversible
    • BThe reaction cannot proceed in either direction
    • CThe reaction is spontaneous
    • DThe forward and reverse reactions are occurring simultaneously
    Show answer & explanation

    Correct answer: D — The forward and reverse reactions are occurring simultaneously

    Reversibility means that both the forward and reverse reactions are simultaneously taking place, establishing the balance necessary for equilibrium.

  14. Q14. A solution with a pH of 7 is considered which type of solution?

    • ABasic
    • BNeutral
    • CStrongly acidic
    • DAcidic
    Show answer & explanation

    Correct answer: B — Neutral

    A pH of 7 signifies that the concentration of hydrogen ions is 10⁻⁷ M, which is the definition of a neutral solution.

  15. Q15. If the concentration of a product is reduced in a system at equilibrium, the system will adjust by shifting the equilibrium towards:

    • AThe side with higher concentration of reactants
    • BThe side with higher concentration of products
    • CThe side with higher temperature
    • DThe side with fewer moles of gas
    Show answer & explanation

    Correct answer: B — The side with higher concentration of products

    Reducing the concentration of a product creates a stress. The system compensates by shifting the reaction in the forward direction (towards the products) to replenish the reduced reactant, thereby increasing the product concentration.

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