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NEET Chemistry: Le Chatelier’s principle Practice Questions

13 free multiple-choice questions on Le Chatelier’s principle (Equilibrium) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. For the equilibrium A(g) + B(g) ⇌ C(g) + D(g), if the concentration of reactant A is increased, the equilibrium will shift towards which side?

    • AThe left side (reactants)
    • BThe right side (products)
    • CThe side with the higher concentration of A
    • DThe side with fewer moles of gas
    Show answer & explanation

    Correct answer: B — The right side (products)

    According to Le Chatelier's principle, if the concentration of a reactant (A) is increased, the system attempts to counteract this change by consuming the added reactant. This causes the equilibrium to shift in the forward direction to consume A and form more products.

  2. Q2. When a product is removed from a system at equilibrium, the system will shift to:

    • AThe left side (reactants).
    • BThe right side (products).
    • CThe reactants will be depleted.
    • DThe same position (no shift).
    Show answer & explanation

    Correct answer: B — The right side (products).

    If a product is removed, the system attempts to replace the removed product by shifting the equilibrium to the right, thus increasing the concentration of the remaining products to re-establish equilibrium.

  3. Q3. Which of the following changes will favor the forward reaction in the equilibrium A + B ⇌ C if the forward reaction is endothermic?

    • ADecreasing the temperature.
    • BIncreasing the concentration of C.
    • CDecreasing the concentration of A.
    • DIncreasing the temperature.
    Show answer & explanation

    Correct answer: D — Increasing the temperature.

    For an endothermic reaction (where heat is a reactant), increasing the temperature shifts the equilibrium to the right (forward direction) to consume the added heat.

  4. Q4. If the concentration of a product is reduced in a system at equilibrium, the system will adjust by shifting the equilibrium towards:

    • AThe side with higher concentration of reactants
    • BThe side with higher concentration of products
    • CThe side with higher temperature
    • DThe side with fewer moles of gas
    Show answer & explanation

    Correct answer: B — The side with higher concentration of products

    Reducing the concentration of a product creates a stress. The system compensates by shifting the reaction in the forward direction (towards the products) to replenish the reduced reactant, thereby increasing the product concentration.

  5. Q5. Consider the reversible equilibrium reaction for the dissociation of a weak electrolyte AB ⇌ A⁺ + B⁻. If an excess amount of solute B⁻ is added to the system, what will be the effect on the equilibrium position?

    • AThe equilibrium will shift to the right
    • BThere will be no change in equilibrium position
    • CThe equilibrium will shift to the left
    • DThe equilibrium will remain unchanged
    Show answer & explanation

    Correct answer: C — The equilibrium will shift to the left

    According to Le Chatelier's principle, when a stress (like adding a substance) is applied to a system at equilibrium, the system shifts in a direction that counteracts that stress. Adding an excess of a product (B⁻) increases the concentration of products, causing the equilibrium to shift in the reverse direction (to the left) to consume the added solute.

  6. Q6. Which change will cause the equilibrium of the reaction A(g) + B(g) ⇌ C(g) to shift to the side with fewer moles of gas?

    • AIncreasing the temperature
    • BIncreasing the pressure
    • CAdding an inert gas
    • DDecreasing the volume
    Show answer & explanation

    Correct answer: B — Increasing the pressure

    Decreasing the volume increases the pressure, which favors the side with fewer moles of gas to alleviate the increased pressure.

  7. Q7. If the temperature of a reversible reaction is increased, the equilibrium will shift in the direction that:

    • AFavors the formation of products
    • BReleases heat (exothermic direction)
    • CAbsorbs heat (endothermic direction)
    • DFavors the formation of reactants
    Show answer & explanation

    Correct answer: C — Absorbs heat (endothermic direction)

    For an endothermic reaction (ΔH > 0), increasing the temperature shifts the equilibrium towards the forward reaction (product formation) to consume the added heat.

  8. Q8. When a change is imposed on a system in equilibrium, the system shifts in a direction that relieves the stress. This statement is known as:

    • AHess's Law
    • BLaw of Conservation of Mass
    • CLe Chatelier's Principle
    • DDalton's Law of Partial Pressures
    Show answer & explanation

    Correct answer: C — Le Chatelier's Principle

    Le Chatelier's principle states that if a change of condition (like concentration, temperature, or pressure) is applied to a system in equilibrium, the system will shift in a direction that counteracts that change to establish a new equilibrium.

  9. Q9. Consider the equilibrium N₂(g) + 3H₂(g) ⇌ 2NH₃(g). If the system is perturbed by adding an inert gas (like Argon) at constant volume, what is the effect on the equilibrium concentration of NH₃?

    • AThe equilibrium shifts to the left
    • BThe equilibrium concentration of NH₃ increases
    • CThe equilibrium concentration of NH₃ decreases
    • DThere is no change in the equilibrium concentration of NH₃
    Show answer & explanation

    Correct answer: D — There is no change in the equilibrium concentration of NH₃

    Adding an inert gas at constant volume changes the total pressure but does not change the partial pressures or the partial concentrations of the reacting gases. Therefore, the equilibrium position remains unchanged.

  10. Q10. What happens to the equilibrium constant (K_c) when the temperature of an equilibrium system is increased?

    • AK_c remains the same
    • BK_c becomes undefined
    • CK_c decreases
    • DK_c increases
    Show answer & explanation

    Correct answer: D — K_c increases

    For an endothermic reaction, increasing the temperature shifts the equilibrium towards the products, increasing K_c. For an exothermic reaction, the reverse happens. In general, a change in temperature affects the equilibrium constant based on the sign of ΔH of the reaction.

  11. Q11. Consider the equilibrium reaction N₂(g) + 3H₂(g) ⇌ 2NH₃(g). If the volume of the container is decreased while keeping the temperature constant, the equilibrium will shift in which direction?

    • AThe equilibrium position remains unchanged
    • BNo change in equilibrium
    • CTo the left (reverse direction)
    • DTo the right (forward direction)
    Show answer & explanation

    Correct answer: C — To the left (reverse direction)

    Decreasing the volume increases the pressure. According to Le Chatelier's principle, the system shifts to reduce the pressure by favoring the side with fewer moles of gas. In this case, the left side (N₂ + 3H₂) has 4 moles of gas, and the right side (NH₃) has 2 moles of gas. Therefore, the equilibrium shifts to the right (forward direction) to relieve the increased pressure.

  12. Q12. Which scenario would cause an equilibrium to shift towards the formation of reactants?

    • AIncreasing the temperature
    • BRemoving a reactant from the system
    • CAdding an inert gas at constant volume
    • DAdding a product to the system
    Show answer & explanation

    Correct answer: B — Removing a reactant from the system

    Removing a reactant from the system decreases its concentration. To counteract this and restore equilibrium, the system shifts in the direction that produces more of that removed reactant, which is the forward direction (towards reactants).

  13. Q13. In the reaction N₂(g) + 3H₂(g) ⇌ 2NH₃(g), if the concentration of NH₃ is increased, the equilibrium will shift:

    • ANo shift occurs
    • BTo the left (reactants)
    • CThe equilibrium position remains unchanged
    • DTo the right (products)
    Show answer & explanation

    Correct answer: B — To the left (reactants)

    When a product concentration is increased, the system shifts in the reverse direction (left) to consume the excess product and re-establish equilibrium.

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