NEET Chemistry: Collision Theory Practice Questions
15 free multiple-choice questions on Collision Theory for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.
Practice thousands more Collision Theory questions in the app →Q1. In the context of bimolecular reactions, what physical attribute of the colliding molecules is crucial for determining their ability to react?
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Correct answer: C — The magnitude of their relative velocity.
While kinetic energy is involved, the relative velocity (which determines the kinetic energy of the collision) is central to determining if the collision meets the threshold criteria set by the activation energy.
Q2. If molecules are assumed to be point masses and ignore rotational and translational energy differences, which postulate of Collision Theory is being implicitly considered?
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Correct answer: B — The molecules are hard spheres with defined interaction volume.
The assumption of point masses and fixed interaction volume relates to the concept of hard spheres and defined collision volume, which simplifies the analysis of molecular interactions.
Q3. Which of the following is the primary requirement for a collision between reactant molecules to be effective in a chemical reaction according to Collision Theory?
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Correct answer: A — The molecules must possess sufficient kinetic energy.
For a collision between reactant molecules to lead to a chemical reaction, they must possess a minimum amount of kinetic energy, known as the activation energy, and collide with the correct orientation.
Q4. The concept of 'collision cross-section' (σ) in Collision Theory relates to which aspect of a reaction?
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Correct answer: C — The effective area for successful collisions
The collision cross-section is the area defined by which collisions between reactant molecules are effective (i.e., they lead to a reaction).
Q5. In collision theory, a chemical reaction can only occur if the colliding molecules possess a certain minimum energy and proper orientation. What factor primarily determines the extent to which collisions lead to a chemical reaction?
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Correct answer: D — The energy of the collisions and the proper orientation
Collision theory states that for a reaction to occur, the colliding molecules must possess energy equal to or greater than the activation energy and must collide with the correct spatial orientation. Therefore, the energy and orientation of the collisions are the deciding factors for reaction occurrence.
Q6. How does increasing the absolute temperature affect the rate of gaseous reactions based on collision theory?
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Correct answer: B — It increases the rate because the average kinetic energy and collision frequency increase.
Increasing the temperature increases the average kinetic energy of the molecules, leading to more frequent collisions and a higher fraction of effective collisions, thus increasing the reaction rate.
Q7. The orientation factor in the context of bimolecular gaseous reactions is important because it accounts for what aspect?
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Correct answer: D — The geometrical arrangement necessary for bond breaking and formation
The orientation factor ensures that the colliding molecules possess the correct spatial alignment (orientation) necessary for the chemical reaction to take place.
Q8. Which statement accurately describes the role of the activation energy (Eₐ) in a bimolecular gaseous reaction according to Collision Theory?
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Correct answer: D — It represents the minimum energy required for the collision to lead to a reaction.
The activation energy (Eₐ) is the minimum energy that must be supplied during a collision for the reaction to take place.
Q9. What is the role of the steric factor in a bimolecular gaseous reaction according to collision theory?
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Correct answer: C — It accounts for the probability that the colliding molecules have the correct spatial orientation.
The steric factor (P) represents the fraction of collisions that occur with the correct orientation required for a reaction to take place.
Q10. Which statement best describes the requirement for a collision to be 'effective' in the context of Collision Theory?
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Correct answer: A — The collision must have sufficient energy and correct orientation.
An effective collision is one that possesses both the minimum required kinetic energy (to overcome Eₐ) and the necessary spatial orientation for bond breaking and formation.
Q11. For a bimolecular reaction to occur successfully according to Collision Theory, what must be satisfied regarding the colliding molecules?
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Correct answer: D — They must collide with sufficient kinetic energy and proper orientation
A collision must have both the necessary minimum kinetic energy (activation energy) and the correct spatial orientation to lead to a chemical reaction.
Q12. Which of the following factors primarily determines the rate of a gaseous reaction according to Collision Theory?
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Correct answer: A — The fraction of collisions that occur with sufficient energy (activation energy)
Collision theory states that for a reaction to occur, molecules must collide with sufficient energy (equal to or greater than the activation energy, Eₐ) and correct orientation. Therefore, the fraction of collisions having sufficient energy is the critical factor determining the reaction rate, not just the total collision frequency or system temperature alone.
Q13. What is the primary requirement for two gaseous molecules to undergo a reaction according to Collision Theory?
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Correct answer: A — They must possess sufficient kinetic energy and proper orientation.
For a reaction to occur, colliding molecules must possess a minimum threshold of kinetic energy (activation energy) and the correct spatial orientation to break existing bonds and form new ones.
Q14. In a bimolecular gaseous reaction, what factor determines the proportion of collisions that lead to a reaction, assuming all molecules are equally likely to collide?
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Correct answer: C — The fraction of molecules with energy greater than Eₐ.
The proportion of successful reactions is governed by the Boltzmann distribution, which dictates the fraction of molecules possessing energy equal to or greater than the activation energy (Eₐ).
Q15. In Collision Theory, what primarily determines the rate of a bimolecular reaction between two gaseous molecules?
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Correct answer: A — The frequency of effective collisions
The rate of a chemical reaction depends on the frequency of collisions between reactant molecules. Effective collisions, those that overcome the activation energy, dictate the reaction rate.
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