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NEET Chemistry: Collision Theory Practice Questions

15 free multiple-choice questions on Collision Theory for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. In the context of bimolecular reactions, what physical attribute of the colliding molecules is crucial for determining their ability to react?

    • AThe number density of the reacting species.
    • BThe total translational energy.
    • CThe magnitude of their relative velocity.
    • DThe overall pressure exerted by the system.
    Show answer & explanation

    Correct answer: C — The magnitude of their relative velocity.

    While kinetic energy is involved, the relative velocity (which determines the kinetic energy of the collision) is central to determining if the collision meets the threshold criteria set by the activation energy.

  2. Q2. If molecules are assumed to be point masses and ignore rotational and translational energy differences, which postulate of Collision Theory is being implicitly considered?

    • AThe frequency of collisions is constant.
    • BThe molecules are hard spheres with defined interaction volume.
    • CThe kinetic energy of molecules is continuously distributed.
    • DThe actual trajectory of the molecules is deterministic.
    Show answer & explanation

    Correct answer: B — The molecules are hard spheres with defined interaction volume.

    The assumption of point masses and fixed interaction volume relates to the concept of hard spheres and defined collision volume, which simplifies the analysis of molecular interactions.

  3. Q3. Which of the following is the primary requirement for a collision between reactant molecules to be effective in a chemical reaction according to Collision Theory?

    • AThe molecules must possess sufficient kinetic energy.
    • BThe molecules must be perfectly aligned in a linear fashion.
    • CMolecules must be in a gaseous state.
    • DThe collision must occur at standard temperature.
    Show answer & explanation

    Correct answer: A — The molecules must possess sufficient kinetic energy.

    For a collision between reactant molecules to lead to a chemical reaction, they must possess a minimum amount of kinetic energy, known as the activation energy, and collide with the correct orientation.

  4. Q4. The concept of 'collision cross-section' (σ) in Collision Theory relates to which aspect of a reaction?

    • AThe total volume occupied by the reactants
    • BThe total energy released during the reaction
    • CThe effective area for successful collisions
    • DThe activation energy required for the reaction
    Show answer & explanation

    Correct answer: C — The effective area for successful collisions

    The collision cross-section is the area defined by which collisions between reactant molecules are effective (i.e., they lead to a reaction).

  5. Q5. In collision theory, a chemical reaction can only occur if the colliding molecules possess a certain minimum energy and proper orientation. What factor primarily determines the extent to which collisions lead to a chemical reaction?

    • AThe total number of collisions per second
    • BThe temperature of the system
    • CThe frequency of collisions between molecules
    • DThe energy of the collisions and the proper orientation
    Show answer & explanation

    Correct answer: D — The energy of the collisions and the proper orientation

    Collision theory states that for a reaction to occur, the colliding molecules must possess energy equal to or greater than the activation energy and must collide with the correct spatial orientation. Therefore, the energy and orientation of the collisions are the deciding factors for reaction occurrence.

  6. Q6. How does increasing the absolute temperature affect the rate of gaseous reactions based on collision theory?

    • AIt increases the rate only if the activation energy is zero.
    • BIt increases the rate because the average kinetic energy and collision frequency increase.
    • CIt decreases the rate because molecules move slower.
    • DIt does not affect the reaction rate as collisions are independent of temperature.
    Show answer & explanation

    Correct answer: B — It increases the rate because the average kinetic energy and collision frequency increase.

    Increasing the temperature increases the average kinetic energy of the molecules, leading to more frequent collisions and a higher fraction of effective collisions, thus increasing the reaction rate.

  7. Q7. The orientation factor in the context of bimolecular gaseous reactions is important because it accounts for what aspect?

    • AThe change in potential energy during collision
    • BThe total kinetic energy of the colliding molecules
    • CThe temperature dependence of the reaction rate
    • DThe geometrical arrangement necessary for bond breaking and formation
    Show answer & explanation

    Correct answer: D — The geometrical arrangement necessary for bond breaking and formation

    The orientation factor ensures that the colliding molecules possess the correct spatial alignment (orientation) necessary for the chemical reaction to take place.

  8. Q8. Which statement accurately describes the role of the activation energy (Eₐ) in a bimolecular gaseous reaction according to Collision Theory?

    • AIt dictates the frequency of collisions between molecules.
    • BIt determines the total number of collisions per unit time.
    • CIt is directly proportional to the reaction rate.
    • DIt represents the minimum energy required for the collision to lead to a reaction.
    Show answer & explanation

    Correct answer: D — It represents the minimum energy required for the collision to lead to a reaction.

    The activation energy (Eₐ) is the minimum energy that must be supplied during a collision for the reaction to take place.

  9. Q9. What is the role of the steric factor in a bimolecular gaseous reaction according to collision theory?

    • AIt specifies the minimum kinetic energy required for reaction.
    • BIt determines the total number of collisions occurring per unit time.
    • CIt accounts for the probability that the colliding molecules have the correct spatial orientation.
    • DIt defines the activation energy of the reaction.
    Show answer & explanation

    Correct answer: C — It accounts for the probability that the colliding molecules have the correct spatial orientation.

    The steric factor (P) represents the fraction of collisions that occur with the correct orientation required for a reaction to take place.

  10. Q10. Which statement best describes the requirement for a collision to be 'effective' in the context of Collision Theory?

    • AThe collision must have sufficient energy and correct orientation.
    • BThe collision must be spontaneous in direction.
    • CThe collision must be exothermic.
    • DThe collision must occur only between molecules of the same type.
    Show answer & explanation

    Correct answer: A — The collision must have sufficient energy and correct orientation.

    An effective collision is one that possesses both the minimum required kinetic energy (to overcome Eₐ) and the necessary spatial orientation for bond breaking and formation.

  11. Q11. For a bimolecular reaction to occur successfully according to Collision Theory, what must be satisfied regarding the colliding molecules?

    • AThey must be moving in the same direction
    • BThey must have the same mass
    • CThey must be in the same phase
    • DThey must collide with sufficient kinetic energy and proper orientation
    Show answer & explanation

    Correct answer: D — They must collide with sufficient kinetic energy and proper orientation

    A collision must have both the necessary minimum kinetic energy (activation energy) and the correct spatial orientation to lead to a chemical reaction.

  12. Q12. Which of the following factors primarily determines the rate of a gaseous reaction according to Collision Theory?

    • AThe fraction of collisions that occur with sufficient energy (activation energy)
    • BThe total number of molecules in the system
    • CThe total kinetic energy of the molecules
    • DThe volume occupied by the reacting gases
    Show answer & explanation

    Correct answer: A — The fraction of collisions that occur with sufficient energy (activation energy)

    Collision theory states that for a reaction to occur, molecules must collide with sufficient energy (equal to or greater than the activation energy, Eₐ) and correct orientation. Therefore, the fraction of collisions having sufficient energy is the critical factor determining the reaction rate, not just the total collision frequency or system temperature alone.

  13. Q13. What is the primary requirement for two gaseous molecules to undergo a reaction according to Collision Theory?

    • AThey must possess sufficient kinetic energy and proper orientation.
    • BThey must be in the same phase.
    • CThey must be in thermal equilibrium.
    • DThey must have zero potential energy.
    Show answer & explanation

    Correct answer: A — They must possess sufficient kinetic energy and proper orientation.

    For a reaction to occur, colliding molecules must possess a minimum threshold of kinetic energy (activation energy) and the correct spatial orientation to break existing bonds and form new ones.

  14. Q14. In a bimolecular gaseous reaction, what factor determines the proportion of collisions that lead to a reaction, assuming all molecules are equally likely to collide?

    • AThe total number of collisions.
    • BThe volume of the container.
    • CThe fraction of molecules with energy greater than Eₐ.
    • DThe total kinetic energy of the system.
    Show answer & explanation

    Correct answer: C — The fraction of molecules with energy greater than Eₐ.

    The proportion of successful reactions is governed by the Boltzmann distribution, which dictates the fraction of molecules possessing energy equal to or greater than the activation energy (Eₐ).

  15. Q15. In Collision Theory, what primarily determines the rate of a bimolecular reaction between two gaseous molecules?

    • AThe frequency of effective collisions
    • BThe total kinetic energy of the molecules
    • CThe temperature of the system
    • DThe total number of molecules present in the container
    Show answer & explanation

    Correct answer: A — The frequency of effective collisions

    The rate of a chemical reaction depends on the frequency of collisions between reactant molecules. Effective collisions, those that overcome the activation energy, dictate the reaction rate.

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