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NEET Chemistry: Pauli's exclusion principle Practice Questions

14 free multiple-choice questions on Pauli's exclusion principle (Atomic Structure) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. If an electron is present in an orbital, what is the fundamental constraint imposed by the Pauli's exclusion principle regarding other electrons in that same orbital?

    • AIt must have higher energy
    • BIt must have opposite spin
    • CIt must occupy a higher principal energy level
    • DIt cannot interact with any other electron
    Show answer & explanation

    Correct answer: B — It must have opposite spin

    The principle mandates that if two electrons share the same spatial location (same orbital), they must have opposite spin states.

  2. Q2. How many electrons can be accommodated in a 2p subshell?

    • A6
    • B2
    • C4
    • D8
    Show answer & explanation

    Correct answer: B — 2

    The 2p subshell has 3 orbitals (2pₓ, 2p_y, 2p_z). Since each orbital can hold a maximum of two electrons (with opposite spins), the total capacity is 3 × 2 = 6 electrons.

  3. Q3. Which of the following statements is a consequence of Pauli's exclusion principle regarding the filling of atomic orbitals?

    • AAll electrons in an orbital must have parallel spins.
    • BAn orbital can hold an infinite number of electrons.
    • CNo two electrons in an atom can have the same set of four quantum numbers.
    • DElectrons can occupy the same spatial location regardless of their spin.
    Show answer & explanation

    Correct answer: C — No two electrons in an atom can have the same set of four quantum numbers.

    Pauli's exclusion principle states that no two electrons in an atom can have identical quantum numbers. This principle fundamentally limits how electrons can be distributed among atomic orbitals, ensuring that only two electrons (with opposite spins) can occupy any single orbital.

  4. Q4. Which pair of electrons can occupy the same spatial region (orbital) in an atom?

    • ATwo electrons with opposite spins and parallel spins
    • BTwo electrons with the same spins
    • CTwo electrons with opposite spins
    • DTwo electrons with parallel spins
    Show answer & explanation

    Correct answer: C — Two electrons with opposite spins

    According to the Pauli's Exclusion Principle, no two electrons in the same orbital can have the same spin. Therefore, they must have opposite spins (one spin up, one spin down) to satisfy the principle.

  5. Q5. Which of the following statements correctly describes Pauli's Exclusion Principle?

    • ANo two electrons can have the same principal quantum number.
    • BElectrons must have opposite spins in the same orbital.
    • CElectrons will always occupy the lowest energy level first.
    • DNo two electrons can have the same four quantum numbers.
    Show answer & explanation

    Correct answer: D — No two electrons can have the same four quantum numbers.

    Pauli's Exclusion Principle states that no two electrons in an atom can have the identical set of four quantum numbers (n, l, mₗ, mₛ).

  6. Q6. Consider the 3d subshell. How many orbitals are available for accommodating electrons based on the Pauli principle?

    • A12
    • B6
    • C9
    • D3
    Show answer & explanation

    Correct answer: C — 9

    The d subshell has 5 degenerate orbitals. According to the Pauli principle, each orbital can hold a maximum of two electrons, allowing a total of 5 × 2 = 10 electrons. (The number of orbitals is 5).

  7. Q7. The Pauli's Exclusion Principle dictates that electrons in the same orbital must have:

    • AIdentical spins
    • BOpposite spins
    • CThe same energy
    • DIdentical magnetic quantum numbers
    Show answer & explanation

    Correct answer: B — Opposite spins

    To satisfy the principle, the two electrons occupying the same spatial region (orbital) must have opposite magnetic spin quantum numbers (mₛ = +1/2 and mₛ = -1/2).

  8. Q8. What is the maximum number of electrons that can be accommodated in a p-subshell?

    • A6
    • B2
    • C14
    • D10
    Show answer & explanation

    Correct answer: A — 6

    The p-subshell has three orbitals (pₓ, p_y, p_z). According to the Pauli principle, each orbital can hold a maximum of two electrons. Therefore, the total capacity is 3 × 2 = 6 electrons.

  9. Q9. What is the fundamental principle that governs the distribution of electrons among atomic orbitals?

    • AHund's Rule
    • BAufbau Principle
    • CPauli's Triplet Rule
    • DPauli's Exclusion Principle
    Show answer & explanation

    Correct answer: D — Pauli's Exclusion Principle

    Pauli's Exclusion Principle states that no two electrons in an atom can have the same set of four quantum numbers.

  10. Q10. In an atomic orbital, the maximum number of electrons that can be accommodated is determined by:

    • AThe magnetic quantum number (mₗ).
    • BThe spin quantum number (mₛ).
    • CThe azimuthal quantum number (l).
    • DThe principal quantum number (n).
    Show answer & explanation

    Correct answer: D — The principal quantum number (n).

    The maximum number of electrons that can be accommodated in a single orbital is two, and the Pauli's principle dictates that these two electrons must have opposite spins. This property is linked to the principal quantum number (n) which defines the energy level.

  11. Q11. How many electrons can be exactly accommodated in a single atomic orbital?

    • A4
    • B2
    • C3
    • D1
    Show answer & explanation

    Correct answer: B — 2

    According to the Pauli's Exclusion Principle, an orbital can hold a maximum of two electrons, and these two electrons must have opposite spins.

  12. Q12. According to Pauli's exclusion principle, what is the maximum number of electrons that can be accommodated in a single orbital?

    • A4
    • B8
    • C2
    • D6
    Show answer & explanation

    Correct answer: C — 2

    An orbital can hold a maximum of two electrons, and these two electrons must have opposite spins (one spin up, one spin down).

  13. Q13. How many electrons can be present in a d subshell?

    • A10
    • B14
    • C2
    • D6
    Show answer & explanation

    Correct answer: C — 2

    A d subshell consists of 5 orbitals (mₗ = -2, -1, 0, 1, 2). Since each orbital can hold 2 electrons, the total capacity is 5 × 2 = 10 electrons.

  14. Q14. The Pauli's exclusion principle primarily restricts the arrangement of electrons based on which pair of quantum numbers?

    • AMagnetic quantum number and spin quantum number
    • BNumber of electrons and shell number
    • CPrincipal quantum number and azimuthal quantum number
    • DOrbital energy and spatial location
    Show answer & explanation

    Correct answer: A — Magnetic quantum number and spin quantum number

    The principle restricts the combination of all four quantum numbers (n, l, mₗ, mₛ). Specifically, it restricts the combination of mₗ and mₛ within the same spatial constraint.

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