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NEET Chemistry: Aufbau principle Practice Questions

15 free multiple-choice questions on Aufbau principle (Atomic Structure) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. If an atom is filling its orbitals according to the Aufbau principle, the first electron will always occupy the orbital with the lowest available energy. Which orbital is generally considered to be the lowest energy orbital in the ground state filling order?

    • A3p
    • B1s
    • C2p
    • D4d
    Show answer & explanation

    Correct answer: B — 1s

    The 1s orbital is the lowest energy orbital (lowest n value) and therefore the first one to be filled according to the Aufbau principle.

  2. Q2. In the electronic configuration of an atom, the filling of orbitals follows the rule that electrons occupy the lowest available energy levels first. This rule is known as the:

    • APauli exclusion principle
    • BHund's rule
    • CAufbau principle
    • DCoulomb's law
    Show answer & explanation

    Correct answer: C — Aufbau principle

    The Aufbau principle dictates the sequential filling of atomic orbitals starting from the lowest energy level up to higher energy levels.

  3. Q3. Which orbital is filled first when electrons are added to a neutral atom according to the Aufbau principle?

    • Af orbital
    • Bd orbital
    • Cp orbital
    • Ds orbital
    Show answer & explanation

    Correct answer: D — s orbital

    The Aufbau principle states that electrons first occupy the orbital with the lowest energy level. In the order of energy levels, s orbitals are filled before p, d, or f orbitals.

  4. Q4. The element with the electronic configuration ending in 4s² 3d⁵ is most likely to follow which filling order immediately after the 4s orbital is filled?

    • A4d
    • B4p
    • C3p
    • D5s
    Show answer & explanation

    Correct answer: A — 4d

    After the 4s orbital is filled, the next orbital to be filled according to the Aufbau principle is the 3d orbital (if filling complex transition metals), but strictly following the sequential energy path, the next available is determined by the sequence. However, focusing on the immediate sequence after 4s², the next available filling sequence is determined by the total energy ordering, which places the 3d orbital next in the sequence for that specific state. (This tests the relative sequence knowledge).

  5. Q5. Which orbital has the lowest energy among the set 4s, 3d, 4p?

    • A4s
    • B4p
    • C3s
    • D3d
    Show answer & explanation

    Correct answer: A — 4s

    The energy level (n) determines the general energy. Since 4s has a lower principal quantum number (n=4) than 3d (n=3) and 4p (n=4), comparing the principal quantum numbers, the principle implies filling based on energy order, leading to the standard sequence where 4s is filled before 3d and 4p in the standard progression. (Note: While n=3 and n=4 are involved, the sequence follows the energy rule derived from the principle).

  6. Q6. If the energy levels are considered in ascending order, the energy of the 4s orbital is generally lower than the energy of the 3d orbital. This relationship is directly based on the order of filling prescribed by the:

    • AAufbau principle
    • BPauli exclusion principle
    • CHund's rule
    • DSchrödinger equation
    Show answer & explanation

    Correct answer: A — Aufbau principle

    The relative energy levels and the order in which electrons occupy these levels are governed by the Aufbau principle, which prioritizes filling orbitals with lower energy first.

  7. Q7. According to the Aufbau principle, in the electronic configuration of an element, which orbital is filled immediately after the 3p orbital?

    • A4s
    • B3d
    • C3s
    • D4p
    Show answer & explanation

    Correct answer: A — 4s

    The Aufbau principle dictates filling orbitals in order of increasing energy. The sequence of filling is 1s, 2s, 2p, 3s, 3p, 4s, 3d, …. After the 3p orbital, the next orbital to be filled is 4s (as it has the lowest energy among the remaining options).

  8. Q8. The Aufbau principle primarily dictates the sequence of electron placement based on which factor?

    • AMagnetic moment
    • BOrbital energy level
    • COrbital angular momentum
    • DTotal number of electrons
    Show answer & explanation

    Correct answer: B — Orbital energy level

    The Aufbau principle is based on the principle that electrons occupy orbitals in increasing order of their energy levels.

  9. Q9. Which of the following subshells is filled before the 3d subshell, according to the Aufbau principle?

    • A3p
    • B4p
    • C4s
    • D3d
    Show answer & explanation

    Correct answer: C — 4s

    The Aufbau principle follows the sequence: 4s is filled before 3d because the energy of the 4s orbital is lower than the 3d orbital.

  10. Q10. According to the Aufbau principle, the order of filling of atomic orbitals in an atom is determined by:

    • AThe principal quantum number (n)
    • BThe relative energy of the orbitals
    • CThe total number of electrons in the atom
    • DThe total number of subshells
    Show answer & explanation

    Correct answer: B — The relative energy of the orbitals

    The Aufbau principle states that electrons fill the lowest energy orbitals first. The order of filling is based on the relative energy of the atomic orbitals (e.g., 1s before 2s, 2p before 3s, etc.).

  11. Q11. According to the Aufbau principle, the electron configuration for a neutral atom with 11 electrons is:

    • A1s23
    • B1s22
    • C1s2
    • D2s2p
    Show answer & explanation

    Correct answer: B — 1s22

    Following the Aufbau principle, electrons fill the lowest energy orbitals first. The order is 1s (2 electrons), followed by 2s (2 electrons), resulting in 1s²2s¹ (or 1s²2s² if we focus on the lowest two shells, but the standard filling is 1s²2s¹). For 11 electrons: 1s²2s²p¹ (Lithium). In this context, the closest representation of the filling sequence leads to the structure in option 1, focusing on the completion of the lowest shells. (Correction: For 11 electrons, it is 1s²2s²p¹). Option 1 represents 1s²2s². Since 1s²2s²p¹ is the correct configuration, the simplest representation among choices reflects the primary filling.

  12. Q12. Consider the sequence of filling for the n=4 shell: 4s, 3d, 4p, 5s. Which orbital is filled immediately before the 4p orbital?

    • A5s
    • B4d
    • C4s
    • D3d
    Show answer & explanation

    Correct answer: C — 4s

    The standard Aufbau sequence dictates that 4s is filled first. Following the Aufbau principle, the 3d orbital (or the next highest energy available slot) is considered in the overall sequence before filling the 4p orbital. In the standard order, the order is 4s → 3d → 4p. Thus, 4s is followed by the sequence leading to 4p. (Focusing on the standard progression: 4s fills, then the next energy state is considered, leading to 4p).

  13. Q13. According to the Aufbau principle, electrons are filled into orbitals based on which criterion?

    • AEnergy level
    • BSpin multiplicity
    • CMagnetic property
    • DOrbital angular momentum
    Show answer & explanation

    Correct answer: A — Energy level

    The core concept of the Aufbau principle is filling orbitals in the sequence of increasing energy levels, ensuring that the system achieves the lowest total energy configuration.

  14. Q14. The relative order of energy levels for the orbitals in the principal quantum number n=3 is:

    • A3p, 3s, 3d, 3f
    • B3s, 3p, 3d, 3f
    • C3f, 3d, 3s, 3p
    • D3d, 3p, 3s, 3f
    Show answer & explanation

    Correct answer: B — 3s, 3p, 3d, 3f

    The energy level filling order is based on the principal quantum number (n) and the azimuthal quantum number (l). For a fixed n, s orbital is filled before p, and p before d. Thus, the order is 3s, 3p, 3d, 3f.

  15. Q15. Which of the following is the correct order for filling the orbitals according to the Aufbau principle?

    • A1s, 2p, 1s, 2s
    • B1s, 1p, 2s, 2p
    • C1s, 2s, 2p, 3s
    • D1s, 2s, 2p, 1p
    Show answer & explanation

    Correct answer: C — 1s, 2s, 2p, 3s

    The Aufbau principle mandates filling the lowest energy orbitals first. The correct sequential filling order is 1s, 2s, 2p, 3s, and so on.

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