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NEET Chemistry: Enthalpy Practice Questions

15 free multiple-choice questions on Enthalpy (Chemical Thermodynamics) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. Which of the following physical quantities is a state function?

    • AWork (W)
    • BInternal Energy (U)
    • CHeat (Q)
    • DEnthalpy (H)
    Show answer & explanation

    Correct answer: D — Enthalpy (H)

    State functions are properties of a system that depend only on the initial and final states, not on the path taken between them. Enthalpy (H) is a state function, while heat (Q) is a path function.

  2. Q2. Which of the following is a state function, meaning its value depends only on the initial and final states of the system, not the path taken:

    • AHeat (q)
    • BInternal Energy (U)
    • CEnthalpy (H)
    • DWork (w)
    Show answer & explanation

    Correct answer: C — Enthalpy (H)

    Enthalpy (H) is a state function. It depends only on the thermodynamic state of the system (pressure, volume, and temperature), making it independent of the process path. Heat (q) is a path function, while Internal Energy (U) is also a state function, but Enthalpy is the specific thermodynamic potential often associated with constant pressure processes.

  3. Q3. For a reaction occurring at constant pressure, the change in enthalpy (ΔH) represents:

    • AThe total energy lost by the system.
    • BThe work done by the surroundings on the system.
    • CThe total energy gained by the surroundings.
    • DThe heat absorbed or released by the system.
    Show answer & explanation

    Correct answer: D — The heat absorbed or released by the system.

    Enthalpy change (ΔH) is precisely the heat absorbed or released by the system during the process when the pressure is constant.

  4. Q4. Enthalpy is a type of thermodynamic property. It is classified as a:

    • AExtrinsic property
    • BPath function
    • CState function
    • DIntensive property
    Show answer & explanation

    Correct answer: C — State function

    Enthalpy is a state function, meaning its value depends only on the initial and final states of the system, not the path taken between them.

  5. Q5. Which of the following statements is true regarding the enthalpy change (ΔH) of a reaction?

    • AΔH depends on the volume change of the system.
    • BΔH is the heat absorbed or released at constant pressure.
    • CΔH is always positive for spontaneous reactions.
    • DΔH is a state function.
    Show answer & explanation

    Correct answer: B — ΔH is the heat absorbed or released at constant pressure.

    Enthalpy change (ΔH) is the heat absorbed or released by the system at constant pressure. It is a state function, meaning the change depends only on the initial and final states, not the path taken.

  6. Q6. The First Law of Thermodynamics is fundamentally based on the principle of:

    • AConservation of Momentum
    • BConservation of Energy
    • CConservation of Mass
    • DConservation of Angular Momentum
    Show answer & explanation

    Correct answer: B — Conservation of Energy

    The First Law of Thermodynamics states that energy cannot be created or destroyed; it is conserved. This principle forms the basis for all enthalpy calculations.

  7. Q7. The enthalpy change of a process is an example of which type of thermodynamic function?

    • APath function
    • BState function
    • CExtrinsic property
    • DIntensive property
    Show answer & explanation

    Correct answer: B — State function

    Enthalpy (H) is a state function, meaning its value depends only on the initial and final states of the system, not on the process taken to reach those states.

  8. Q8. Which of the following quantities is a state function?

    • AWork (w)
    • BInternal Energy (U)
    • CHeat (q)
    • DEnthalpy (H)
    Show answer & explanation

    Correct answer: D — Enthalpy (H)

    A state function is a property that depends only on the current state of the system, not the path taken. Enthalpy (H) is a state function, whereas heat (q) and work (w) are path functions.

  9. Q9. The molar enthalpy of formation (ΔH_f°) of an element in its most stable state at standard conditions (1 bar and 298 K) is defined as:

    • AThe heat released when the element is burned completely in oxygen.
    • BThe heat absorbed when one mole of the element is formed from its elements in their standard states.
    • CThe enthalpy change of the system when it is placed in an external heat bath.
    • DThe enthalpy change when a reaction occurs reversibly at constant volume.
    Show answer & explanation

    Correct answer: B — The heat absorbed when one mole of the element is formed from its elements in their standard states.

    The standard enthalpy of formation (ΔH_f°) is the enthalpy change when one mole of a compound is formed from its constituent elements in their respective standard states.

  10. Q10. If the enthalpy of a reaction is negative (ΔH < 0), the reaction is classified as:

    • AExothermic
    • BEndothermic
    • CIsothermal
    • DAdiabatic
    Show answer & explanation

    Correct answer: A — Exothermic

    A negative enthalpy change (ΔH < 0) indicates that the system releases energy to the surroundings, which defines an exothermic process. An endothermic reaction has a positive ΔH.

  11. Q11. The enthalpy of reaction (ΔH) is defined as the heat absorbed or released by the system during a process carried out at constant pressure. What is the standard unit for enthalpy change?

    • AJoules per mole (J/mol)
    • BKilojoules per mole (kJ/mol)
    • CJoules (J)
    • DKilojoules (kJ)
    Show answer & explanation

    Correct answer: B — Kilojoules per mole (kJ/mol)

    Enthalpy is a form of energy. The standard SI unit for energy is the Joule (J). For enthalpy change, the standard unit is kilojoules per mole (kJ/mol) or joules per mole (J/mol).

  12. Q12. Which of the following quantities is NOT a state function in thermodynamics?

    • AInternal Energy (U)
    • BGibbs Free Energy (G)
    • CHeat (Q)
    • DEnthalpy (H)
    Show answer & explanation

    Correct answer: C — Heat (Q)

    Heat (Q) is a path function, meaning its value depends on the process taken between two states, whereas Enthalpy (H), Internal Energy (U), and Gibbs Free Energy (G) are state functions.

  13. Q13. The enthalpy change (ΔH) for a process is defined as the change in:

    • AInternal Energy
    • BHeat exchanged at constant pressure
    • CWork done
    • DEntropy
    Show answer & explanation

    Correct answer: B — Heat exchanged at constant pressure

    Enthalpy (H) is defined as H = U + PV. Therefore, the change in enthalpy (ΔH) is equal to the heat exchanged (qₚ) under constant pressure.

  14. Q14. Hess's Law is a consequence of which fundamental thermodynamic principle?

    • AThird Law of Thermodynamics
    • BSecond Law of Thermodynamics
    • CFirst Law of Thermodynamics
    • DZeroth Law of Thermodynamics
    Show answer & explanation

    Correct answer: C — First Law of Thermodynamics

    Hess's Law states that the total enthalpy change for a chemical reaction is the same regardless of the path taken, which is a direct consequence of the First Law of Thermodynamics (conservation of energy).

  15. Q15. Which of the following statements is correct regarding the enthalpy change (ΔH) for a chemical reaction that occurs in a closed system?

    • AThe enthalpy change is independent of the path taken by the reaction.
    • BFor a closed system, ΔH is equal to the heat absorbed by the system only.
    • CΔH is solely dependent on the change in internal energy of the system.
    • DΔH represents the total heat exchanged with the surroundings during the reaction.
    Show answer & explanation

    Correct answer: D — ΔH represents the total heat exchanged with the surroundings during the reaction.

    Enthalpy change (ΔH) is the heat exchanged during a process at constant pressure. In a closed system, it represents the heat absorbed or released by the system due to the reaction. Options A and C are incomplete or incorrect definitions. Option B captures the essence of enthalpy as the heat interaction with the surroundings (the environment).

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