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NEET Chemistry: Inner Transition Elements (Lanthanoids and Actinoids) Practice Questions

15 free multiple-choice questions on Inner Transition Elements (Lanthanoids and Actinoids) (d- and f-Block Elements) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. The general electronic configuration for the Lanthanides elements is:

    • Ans² (n-1)d²
    • Bns² (n-1)d¹
    • Cns²
    • D(n-1)d¹s²
    Show answer & explanation

    Correct answer: C — ns²

    Lanthanides are characterized by the filling of the 4f orbitals, following the general configuration of the preceding elements (ns²).

  2. Q2. Which block of the periodic table contains the Lanthanides and Actinides?

    • Ap-block
    • Bd-block
    • Cd-f-block
    • Df-block
    Show answer & explanation

    Correct answer: D — f-block

    The Lanthanides and Actinides are the elements filling the f-orbitals, which correspond to the f-block of the periodic table.

  3. Q3. The Lanthanoid contraction primarily affects the atomic radii of elements in which series?

    • Ad-block elements
    • Bf-block elements
    • Cs-block elements
    • DTransition elements
    Show answer & explanation

    Correct answer: B — f-block elements

    The lanthanoid contraction is the gradual decrease in atomic radii observed across the lanthanoid series (f-block elements) due to poor shielding by the filling 4f orbitals.

  4. Q4. Which element among the Actinoids is generally known to be the most radioactive among the first row?

    • ANeptunium
    • BThorium
    • CUranium
    • DPlutonium
    Show answer & explanation

    Correct answer: C — Uranium

    Uranium (U) is the most well-known and commonly studied radioactive element among the Actinoids.

  5. Q5. Which statement is true regarding the general magnetic properties of the Lanthanoid series?

    • AThe magnetic properties are generally complex and depend on the specific element
    • BThey follow the pattern of d-block elements exactly
    • CAll lanthanoids are paramagnetic
    • DAll lanthanoids are diamagnetic
    Show answer & explanation

    Correct answer: A — The magnetic properties are generally complex and depend on the specific element

    The magnetic behavior of lanthanoids is complex, often exhibiting both paramagnetic and diamagnetic properties depending on the specific ion and crystal field environment.

  6. Q6. The Lanthanoid contraction primarily results in the decrease in which property as one moves across the series?

    • AAtomic radius
    • BIonization energy
    • CElectronegativity
    • DMelting point
    Show answer & explanation

    Correct answer: A — Atomic radius

    Lanthanoid contraction causes a steady decrease in the atomic radii of the elements as the atomic number increases, especially noticeable in the lanthanide series.

  7. Q7. Which element is the last element in the Actinoid series?

    • ALawrencium (Lr)
    • BUranium (U)
    • CNeptunium (Np)
    • DPlutonium (Pu)
    Show answer & explanation

    Correct answer: A — Lawrencium (Lr)

    Lawrencium (Lr) is the last element in the Actinoid series, completing the sequence of the f-block elements.

  8. Q8. The Lanthanoid elements (f-block) are primarily characterized by the involvement of which type of orbital in chemical bonding?

    • As-orbitals
    • Bd-orbitals
    • Cf-orbitals
    • Dp-orbitals
    Show answer & explanation

    Correct answer: C — f-orbitals

    The chemical properties of the lanthanoids are largely determined by the spatial extension and participation of the 4f orbitals in bonding and magnetic properties. These 4f orbitals are often poorly shielded and relatively diffuse, allowing for unique electronic configurations.

  9. Q9. Which of the following represents the general filling order of the f-orbitals in the actinoid series?

    • A6d¹ to 6d¹⁰
    • B5d¹ to 5d¹⁰
    • C5f¹ to 5f¹⁴
    • D7p⁶ to 7p⁶
    Show answer & explanation

    Correct answer: C — 5f¹ to 5f¹⁴

    The general filling order within the actinoid series follows the sequential filling of the 5f orbitals, which is the fundamental basis for the structure of the series.

  10. Q10. Which of the following elements belongs to the Actinoid series?

    • AGadolinium (Gd)
    • BLanthanum (La)
    • CActinium (Ac)
    • DEuropium (Eu)
    Show answer & explanation

    Correct answer: C — Actinium (Ac)

    Actinium (Ac) is the first element in the Actinoid series, marking the beginning of the series that includes elements like Thorium, Uranium, etc.

  11. Q11. Which of the following statements accurately describes the trend observed in the atomic radii of the lanthanoid series (La to Lu)?

    • AThe atomic radii remain nearly constant due to the shielding effect of the d-electrons.
    • BThe atomic radii decrease slightly due to the lanthanoid contraction.
    • CThe atomic radii increase steadily due to the poor shielding of 4f-electrons.
    • DThe atomic radii decrease steadily due to increasing effective nuclear charge.
    Show answer & explanation

    Correct answer: B — The atomic radii decrease slightly due to the lanthanoid contraction.

    The lanthanoid contraction is the progressive decrease in atomic and ionic radii across the lanthanoid series. This occurs because the poor shielding effect of the newly filled 4f-orbitals causes the effective nuclear charge experienced by the outer electrons to increase, pulling them closer to the nucleus.

  12. Q12. Which element in the actinoid series exhibits the highest tendency to form stable oxidation states involving the 5f orbitals?

    • APlutonium (Pu)
    • BAmericium (Am)
    • CUranium (U)
    • DNeptunium (Np)
    Show answer & explanation

    Correct answer: A — Plutonium (Pu)

    Actinoids, especially those in the heavier elements, exhibit varied and sometimes higher oxidation states due to the energetic availability of the 5f electrons, which are more diffuse and participate more actively in bonding than d electrons, compared to the lanthanoids. Plutonium (Pu) is often cited for complex bonding capabilities in this series.

  13. Q13. Which set of elements is generally characterized by the filling of the 4f and 5f orbitals, leading to the characteristic properties of the Lanthanoids and Actinoids?

    • Ap-block
    • Bs-block
    • Cd-block
    • Df-block
    Show answer & explanation

    Correct answer: D — f-block

    The Lanthanoids and Actinoids are the elements found in the f-block (or inner transition elements). They are defined by the partially filled f-orbitals (4f for lanthanoids and 5f for actinides).

  14. Q14. The elements in the f-block are characterized by the filling of which specific orbital type?

    • As-orbitals
    • Bd-orbitals
    • Cf-orbitals
    • Dp-orbitals
    Show answer & explanation

    Correct answer: C — f-orbitals

    The characteristic feature of the f-block elements (Lanthanoids and Actinoids) is the filling of the subshell orbitals denoted by 'f'.

  15. Q15. Which of the following elements is the first element in the actinoid series?

    • AUranium (U)
    • BPlutonium (Pu)
    • CAmericium (Am)
    • DNeptunium (Np)
    Show answer & explanation

    Correct answer: B — Plutonium (Pu)

    The actinoid series begins with the element Uranium (U), which has atomic number 92. While Neptunium (Np) and Plutonium (Pu) are actinides, Uranium is the starting point of the actinoid series.

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