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NEET Chemistry: Hybridization Practice Questions

15 free multiple-choice questions on Hybridization (Chemical Bonding and Molecular Structure) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. A central atom hybridized in the sp² state forms how many sigma (σ) bonds?

    • A2
    • B4
    • C3
    • D5
    Show answer & explanation

    Correct answer: D — 5

    In sp² hybridization, one s orbital and two p orbitals mix to form three equivalent sp² hybrid orbitals. These three orbitals are used to form three σ bonds.

  2. Q2. In the molecule of water (H₂O), the central oxygen atom exhibits which type of hybridization, which dictates its molecular geometry?

    • Ad²sp³
    • Bsp
    • Csp³
    • Dsp²
    Show answer & explanation

    Correct answer: C — sp³

    The central oxygen atom in water forms two sigma (σ) bonds and two lone pairs, resulting in four electron domains. This configuration requires four hybrid orbitals, which corresponds to sp³ hybridization. The resulting geometry is tetrahedral.

  3. Q3. The hybridization state sp³ corresponds to a total of how many electron domains around the central atom?

    • A4
    • B5
    • C3
    • D2
    Show answer & explanation

    Correct answer: B — 5

    sp³ hybridization involves four hybrid orbitals, which correspond to four electron domains (four bonding regions) around the central atom.

  4. Q4. A molecule that is sp² hybridized will contain which type of bond?

    • AOnly δ bonds
    • BPurely π bonds
    • CBoth σ and π bonds
    • DPurely σ bonds
    Show answer & explanation

    Correct answer: C — Both σ and π bonds

    sp² hybridization involves the mixing of one s orbital and two p orbitals. This results in one σ bond and one π bond (the remaining unhybridized p orbital forms the π bond).

  5. Q5. In sp hybridization, how many hybrid orbitals are formed?

    • A5
    • B2
    • C3
    • D4
    Show answer & explanation

    Correct answer: B — 2

    sp hybridization involves the mixing of one s orbital and one p orbital, resulting in two equivalent hybrid orbitals.

  6. Q6. What is the preferred bond angle in a molecule exhibiting sp³ hybridization?

    • A180°
    • B120°
    • C109.5°
    • D102°
    Show answer & explanation

    Correct answer: C — 109.5°

    The sp³ hybrid orbitals arrange themselves to maximize separation, resulting in a tetrahedral angle of 109.5°.

  7. Q7. Which compound exhibits a geometry resulting from sp³ hybridization where all bond angles are equal to 109.5°?

    • ABF₃
    • BNH₃
    • CBeCl₂
    • DPCl₅
    Show answer & explanation

    Correct answer: B — NH₃

    Ammonia (NH₃) has three bonding domains and one lone pair, fitting the sp³ description, which results in a trigonal pyramidal geometry with bond angles close to the ideal tetrahedral angle of 109.5°.

  8. Q8. The bond angle in a molecule with sp² hybridization is typically what, considering lone pair repulsion?

    • A109.5°
    • B107°
    • C120°
    • D180°
    Show answer & explanation

    Correct answer: C — 120°

    Although the ideal angle for sp² systems is 120°, the presence of lone pairs (or lone pair repulsion) slightly reduces this angle, meaning the actual angle is slightly less than 120°.

  9. Q9. Which of the following molecules exhibits sp³ hybridization?

    • ABeCl₂
    • BBF₃
    • CCO₂
    • DNH₃
    Show answer & explanation

    Correct answer: D — NH₃

    Ammonia (NH₃) has a central nitrogen atom with four electron domains (three bonds and one lone pair), requiring sp³ hybridization.

  10. Q10. In the sp hybridization state, how many hybrid orbitals are involved in the formation of the bond structure?

    • AOne
    • BFour
    • CTwo
    • DThree
    Show answer & explanation

    Correct answer: C — Two

    sp hybridization involves mixing one s orbital and one p orbital, resulting in two equivalent sp hybrid orbitals.

  11. Q11. Which hybridization state is associated with a bond angle of 120°?

    • Asp2
    • Bsp3
    • Csp
    • Dd²sp3
    Show answer & explanation

    Correct answer: A — sp2

    The sp² hybridization results in a trigonal planar geometry with bond angles of 120°.

  12. Q12. The geometry adopted by a molecule like ethene (C₂H₄), which is derived from sp² hybridization, is:

    • ATrigonal Planar
    • BTetrahedral
    • CLinear
    • DPyramidal
    Show answer & explanation

    Correct answer: A — Trigonal Planar

    sp² hybridization leads to a trigonal planar electron geometry, which results in a trigonal planar molecular shape (bond angle ≈ 120°).

  13. Q13. The bond angle in a molecule exhibiting sp³d² hybridization is usually closest to which value?

    • A180°
    • B120°
    • C107°
    • D109.5°
    Show answer & explanation

    Correct answer: D — 109.5°

    sp³d² hybridization involves a more complex arrangement than simple sp³, and the resulting bond angles are generally found around the tetrahedral value of 109.5°, though the exact geometry is distorted.

  14. Q14. In the sp³ hybridization state, the bond angle in a typical tetrahedral geometry is:

    • A180°
    • B109.5°
    • C90°
    • D120°
    Show answer & explanation

    Correct answer: B — 109.5°

    sp³ hybridization results in a tetrahedral electron geometry, and the ideal bond angle for a tetrahedron is 109.5°.

  15. Q15. Which type of hybridization is associated with the formation of three equivalent σ bonds and results in a tetrahedral geometry?

    • Asp³
    • Bsp
    • Csp²
    • Dd²sp³
    Show answer & explanation

    Correct answer: A — sp³

    sp³ hybridization involves mixing one s orbital and three p orbitals to form four equivalent sp³ hybrid orbitals, resulting in a tetrahedral geometry (bond angle ≈ 109.5°).

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