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NEET Chemistry: Covalent Bonding Practice Questions

14 free multiple-choice questions on Covalent Bonding (Chemical Bonding and Molecular Structure) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. What is the shape of the molecule of water (H₂O)?

    • ALinear
    • BTrigonal Planar
    • CTetrahedral
    • DBent
    Show answer & explanation

    Correct answer: D — Bent

    The central Oxygen atom has two bonding pairs and two lone pairs (four electron domains). According to VSEPR theory, the molecular geometry is bent.

  2. Q2. Which type of bond is characterized by the overlap of atomic orbitals along the internuclear axis?

    • ACoordinate bond
    • BIonic bond
    • CSigma (σ) bond
    • DPi (π) bond
    Show answer & explanation

    Correct answer: C — Sigma (σ) bond

    Sigma (σ) bonds are formed by the end-to-end overlap of atomic orbitals along the internuclear axis, forming the strongest component of a covalent bond.

  3. Q3. A bond between two atoms is considered polar if the difference in electronegativity between them is:

    • ALarge
    • BSmall
    • CEqual
    • DZero
    Show answer & explanation

    Correct answer: A — Large

    A large difference in electronegativity (greater than a threshold value) indicates unequal sharing, leading to a polar bond.

  4. Q4. In a diatomic molecule like H₂, the bond is formed by:

    • AElectrostatic attraction
    • BDipole-dipole interaction
    • CSharing of electrons
    • DTransfer of electrons
    Show answer & explanation

    Correct answer: C — Sharing of electrons

    Diatomic molecules form covalent bonds through the sharing of electrons.

  5. Q5. Which statement correctly describes a covalent bond?

    • ASharing of electrons between atoms.
    • BAttraction between nuclei of different elements.
    • CElectrostatic attraction between oppositely charged ions.
    • DTransfer of electrons between atoms.
    Show answer & explanation

    Correct answer: A — Sharing of electrons between atoms.

    A covalent bond is formed by the mutual sharing of valence electrons between atoms.

  6. Q6. In a molecule, the bond order is defined by the number of shared electron pairs. For a triple bond, how many electron pairs are shared between the two bonded atoms?

    • AOne pair
    • BThree pairs
    • CTwo pairs
    • DFour pairs
    Show answer & explanation

    Correct answer: B — Three pairs

    A triple bond implies that three pairs of electrons are shared between the two participating atoms.

  7. Q7. Which of the following correctly describes the nature of a covalent bond?

    • AIt is solely due to the presence of d-orbitals in the atoms involved.
    • BIt involves the complete transfer of electrons between atoms.
    • CIt arises from the mutual sharing of valence electrons between atoms.
    • DIt is formed by the electrostatic attraction between oppositely charged ions.
    Show answer & explanation

    Correct answer: C — It arises from the mutual sharing of valence electrons between atoms.

    Covalent bonds are formed when atoms share their valence electrons to achieve a stable configuration, resulting in mutual sharing.

  8. Q8. The bond formed between two atoms with very different electronegativities is likely to be:

    • ANon-polar covalent
    • BMetallic
    • CPolar covalent
    • DIonic
    Show answer & explanation

    Correct answer: C — Polar covalent

    When there is a significant difference in electronegativity (typically > 0.4 to 1.7), the bond exhibits partial ionic character, making it polar covalent.

  9. Q9. When two atoms form a bond, the bond length is inversely related to the bond order. If the bond order increases, what happens to the bond length?

    • AIncreases
    • BStays the same
    • CBecomes zero
    • DDecreases
    Show answer & explanation

    Correct answer: D — Decreases

    Higher bond order means more shared electrons, leading to stronger attraction and a shorter equilibrium bond length.

  10. Q10. In the molecule of CH₄, the hybridization of the central carbon atom is:

    • Asp²
    • Bsp
    • Csp³d
    • Dsp³
    Show answer & explanation

    Correct answer: D — sp³

    Methane (CH₄) has four sigma bonds and no lone pairs around the central carbon, resulting in sp³ hybridization.

  11. Q11. In a structure where atoms share electrons unequally, the resulting bond is classified as which type of covalent bond?

    • AIonic covalent
    • BNonpolar covalent
    • CCoordinate covalent
    • DPolar covalent
    Show answer & explanation

    Correct answer: D — Polar covalent

    When there is an unequal sharing of electrons due to different electronegativities, the bond is polar covalent.

  12. Q12. Which type of covalent bond is characterized by the largest shared electron density between two atoms?

    • AIonic bond
    • BSigma (σ) bond
    • CCoordinate bond
    • DPi (π) bond
    Show answer & explanation

    Correct answer: B — Sigma (σ) bond

    Sigma (σ) bonds result from the head-on overlap of atomic orbitals and involve the largest shared electron density.

  13. Q13. In the structure of ammonia (NH₃), the geometry around the nitrogen atom is:

    • APyramidal
    • BLinear
    • CTrigonal Planar
    • DTetrahedral
    Show answer & explanation

    Correct answer: A — Pyramidal

    The nitrogen atom has three bonding pairs and one lone pair (four electron domains). This arrangement results in a pyramidal molecular geometry.

  14. Q14. The molecular structure is determined by the arrangement of atoms and the nature of the covalent bonds, which dictates the shape of the molecule. This concept is primarily governed by:

    • AValence Bond Theory
    • BLattice energy
    • CIonization energy
    • DMetallic bonding
    Show answer & explanation

    Correct answer: A — Valence Bond Theory

    Valence Bond Theory, which deals with the formation and arrangement of covalent bonds, is fundamental to determining molecular structure.

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