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NEET Chemistry: Periodic trends and properties of elements Practice Questions

13 free multiple-choice questions on Periodic trends and properties of elements (Classification of Elements and Periodicity in Properties) for NEET Chemistry, each with the correct answer and a step-by-step explanation. Attempt a question, then reveal the solution to check your reasoning.

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  1. Q1. Which periodic trend describes the energy required to remove the most loosely bound electron from an isolated gaseous atom?

    • AElectron Gain Enthalpy
    • BElectronegativity
    • CElectron Affinity
    • DIonization Energy
    Show answer & explanation

    Correct answer: D — Ionization Energy

    Ionization Energy (IE) is the energy required to remove an electron from an atom. IE generally increases across a period and decreases down a group.

  2. Q2. As we move from left to right across a period in the periodic table, the atomic size generally:

    • AIncreases
    • BDecreases
    • CFluctuates randomly
    • DRemains constant
    Show answer & explanation

    Correct answer: B — Decreases

    As the number of protons in the nucleus increases, the effective nuclear charge increases, pulling the electron cloud closer, thus decreasing the atomic size.

  3. Q3. Which of the following pairs correctly represents the trend in atomic radius as we move from left to right across a period in the periodic table?

    • AFluctuates randomly
    • BIncreases consistently
    • CDecreases consistently
    • DRemains the same
    Show answer & explanation

    Correct answer: C — Decreases consistently

    As we move across a period (left to right), the number of protons increases, leading to a stronger effective nuclear charge, which pulls the electrons closer to the nucleus, thus decreasing the atomic radius.

  4. Q4. Which element has the highest electronegativity value?

    • ANitrogen
    • BFluorine
    • COxygen
    • DChlorine
    Show answer & explanation

    Correct answer: B — Fluorine

    Electronegativity is the tendency of an atom to attract a bonding pair of electrons. Fluorine (F) is the most electronegative element in the periodic table.

  5. Q5. Which property generally decreases as we move down a group in the periodic table?

    • AMetallic character
    • BValency
    • CAtomic Radius
    • DIonization Energy
    Show answer & explanation

    Correct answer: D — Ionization Energy

    Ionization energy decreases down a group because the valence electrons are further from the nucleus and are shielded by more inner-shell electrons, making them easier to remove.

  6. Q6. Which of the following elements has the largest atomic radius?

    • APotassium
    • BSodium
    • CRubidium
    • DLithium
    Show answer & explanation

    Correct answer: C — Rubidium

    Atomic radius increases as we move down a group because the number of electron shells increases, leading to greater distance from the nucleus. Rubidium (Rb) is the heaviest alkali metal listed and has the largest size among these.

  7. Q7. Which element among the following exhibits the largest electron gain enthalpy (most negative value)?

    • AMagnesium
    • BLithium
    • CSodium
    • DChlorine
    Show answer & explanation

    Correct answer: D — Chlorine

    Electron gain enthalpy (or energy) is generally more negative (indicating a greater release of energy upon gaining an electron) for elements on the right side of the periodic table, especially halogens. Chlorine (Cl) typically has a larger gain than the alkali metals.

  8. Q8. Which of the following correctly describes the general trend observed in the first ionization enthalpy (IE₁) when moving from left to right across a period in the periodic table?

    • AIt remains constant
    • BIt increases continuously
    • CIt first increases and then decreases
    • DIt decreases continuously
    Show answer & explanation

    Correct answer: B — It increases continuously

    As we move across a period, the effective nuclear charge increases, pulling the valence electrons more strongly. This makes it harder to remove an electron, thus the first ionization enthalpy (IE₁) generally increases across a period.

  9. Q9. As we move down a group in the periodic table, the atomic size generally:

    • AIncreases
    • BFluctuates randomly
    • CDecreases
    • DRemains constant
    Show answer & explanation

    Correct answer: A — Increases

    As we move down a group, the principal quantum number increases, adding new electron shells. This results in a significant increase in atomic size.

  10. Q10. The general trend for the electron gain enthalpy (or electron affinity) is:

    • ARemains constant
    • BDecreases across a period
    • CDecreases down a group
    • DIncreases down a group
    Show answer & explanation

    Correct answer: C — Decreases down a group

    Electron gain enthalpy generally becomes less exothermic (less negative) as you move down a group because the valence shell is further from the nucleus, making the attraction less effective.

  11. Q11. Which pair of elements has the smallest difference in electronegativity?

    • ALi and Na
    • BMg and Al
    • CO and F
    • DC and N
    Show answer & explanation

    Correct answer: A — Li and Na

    The difference in electronegativity is smallest between elements in the same group, particularly where the difference in nuclear charge is minimal. Mg and Al are adjacent metals with relatively similar properties compared to C/N or O/F differences.

  12. Q12. Which statement accurately describes the trend in electronegativity down a group in the periodic table?

    • AElectronegativity increases as atomic size increases
    • BElectronegativity decreases as atomic size increases
    • CElectronegativity is inversely proportional to atomic size
    • DElectronegativity remains constant down the group
    Show answer & explanation

    Correct answer: B — Electronegativity decreases as atomic size increases

    Electronegativity decreases down a group because the atomic size increases, meaning the nucleus has less effective pull on the valence electrons.

  13. Q13. Which element has the highest first ionization enthalpy among the elements in the second period (Li to Ne)?

    • ABoron (B)
    • BNeon (Ne)
    • CBeryllium (Be)
    • DLithium (Li)
    Show answer & explanation

    Correct answer: B — Neon (Ne)

    Ionization enthalpy generally increases across a period because the effective nuclear charge increases, making it harder to remove an electron. Neon (Ne) has the highest ionization enthalpy in the second period.

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